Mehmet KOBYA

Article | 2023 | Ultrasonics Sonochemistry98

The carbonous-based nanocomposites of CoCr layered double hydroxide (LDH) with graphene oxide (GO) and reduced graphene oxide (rGO) were prepared. The successful synthesis of the CoCr LDH in hydrotalcite crystalline structure was deduced from the pattern obtained from X-ray diffraction, and the chemical composition of its surface was checked by X-ray photoelectron spectroscopy. The prosperous decorating of LDH on the sheets of rGO and GO was authenticated by the energy dispersive X-ray spectroscopy analysis and micrographs of scanning electron and transmission electron microscopy. The photo-assisted sonocatalytic activity of the pre . . .pared nanocomposites was appraised for the decomposition of dimethyl phthalate (DMP) as a plasticizer. The highest decomposition efficiency of 100% was obtained in the existence of CoCr LDH/rGO nanocomposite (0.5 g/L) during 20 min of reaction time via photo-assisted sonocatalysis. The rGO improved the catalytic activity of the CoCr LDH by increasing the specific surface area from 1.2 m2/g to 4.5 m2/g and reducing the band gap from 1.7 eV to 1.3 eV. Moreover, the results of the colony-forming unit method endorsed antibacterial property improvement of the CoCr LDH via hybridizing with rGO. The results of this research provide an optimistic perspective for applying carbonous-based nanocomposites of CoCr LDH as a novel catalyst with antibacterial properties in photo-assisted sonocatalytic processes. Keyword: advanced oxidation process; graphene oxide; layered double hydroxide; photocatalysis; sonocatalysi More less

Mehmet KOBYA

Article | 2023 | Ultrasonics Sonochemistry95

This study is the first to explore the possibility of utilizing CuCr LDH decorated on reduced graphene oxide (rGO) and graphene oxide (GO) as sonophotocatalysts for the degradation of dimethyl phthalate (DMP). CuCr LDH and its nanocomposites were successfully fabricated and characterized. Scanning electron microscopy (SEM) along with high-resolution transmission electron microscope (HRTEM) both evidenced the formation of randomly oriented nanosheet structures of CuCr LDH coupled with thin and folded sheets of GO and rGO. The impact of diverse processes on the degradation efficiency of DMP in the presence of the so-prepared catalysts . . . was compared. Benefiting from the low bandgap and high specific surface area, the as-obtained CuCr LDH/rGO represented outstanding catalytic activity (100 ) toward 15 mg L−1 of DMP within 30 min when subjected to light and ultrasonic irradiations simultaneously. Radical quenching experiments and visual spectrophotometry using an O-phenylenediamine revealed the crucial role of hydroxyl radicals compared to holes and superoxide radicals. Overall, outcomes disclosed that CuCr LDH/rGO is a stable and proper sonophotocatalyst for environmental remediation. Keywords: Layered double hydroxide, Graphene, Advanced oxidation processes, Sonophotocatalysis, Dimethyl phthalat More less

Mehmet KOBYA

Article | 2022 | Ultrasonics Sonochemistry82

In this study, ZnCr layered double hydroxide (LDH), ZnCr LDH/carbon nanotube (CNT), and ZnCr LDH/Biochar (BC) were synthesized and characterized by various analyses. The successful synthesis and the great crystallinity of the samples were consented by XRD analysis. SEM and TEM were applied to study the morphology of the synthesized samples. The simultaneous presence of C, Zn, and Cr elements was well confirmed by EDX and dot mapping analyses demonstrating the successful preparation of nanocomposites. According to the BET analysis, ZnCr LDH nanocomposites with BC and CNT had more specific surface area compared to ZnCr LDH alone. The . . .catalytic performances of the samples were determined for the degradation of rifampicin (RF). The degradation efficiency of the sonophotocatalytic process in the presence of 0.6 g L-1 of ZnCr LDH/BC toward 15 mg L-1 of RF under 150 W ultrasound and visible light irradiation was found to be about 100 within 40 min. The influence of the reactive species on the sonophotocatalytic process was assessed via the addition of different scavengers (para- benzoquinone (p-BQ), formic acid (FA), isopropyl alcohol (IPA)), and enhancers (hydrogen peroxide and potassium persulfate). The GC-MS analysis was carried out and eleven by-products during the RF decomposition were detected More less